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MATERIAL SAFETY DATA SHEET( form according to EEC Directive 93/112/EC)
NAME: LITHIUM-ION RECHARGABLE BATTERIES

 
1.IDENTIFICATION (of the product and the supplier)
1.1 Product:  None-explosive  Rechargeable battery

Trade name and model : LITHIUM-ION POWER BATTERY

IEC designation : 
Models : TS-LCP , TS-LYP , TS-LMP

Electrochemical system : Lithium , Phosphor , Iron , Fluorine Compound

Electrodes Negative electrode
Carbon/Graphite
Nano Cellulose
Positive electrode
LiFCoO 2
LiFeYPO4
LiFNiMnCoO2
        Binder

        SoLvent

·Electrolyte

Solution of Lithium hexafluorophosphate (LiPF 6 )
In a mixture of organic solvents**

· Electrolyte

3.6 Volts

*Equivalent name: lithiated cobalt oxide.
** Ethylene Carbonate (EC) + DiEthyl Carbonate (DMC) + DiEthyl Carbonate (DEC) + Ethyl Acetate (EA).

1.2 Supplier:
Name : Thunder Sky Battery Ltd.
Address : Thunder Sky Industrial Base,No.3 Industrial Zone,Lisonglang,Village,
Gongming Town, Bao’an Dist, Shenzhen, P.R.C
Phone: + 86 755 86026789    Fax: +86 755 86026678

1.3 Emergency contact:
CHEMTREC Phone: 1-800-424-9300

2 -
Battery Material Elements and Index

 LCP

LYP

 LMP

Chemical

Element

 Index

Chemical

Element

 Index

Chemical

Element

 Index

 Fe

 0.005%

 Fe

 42%

 Fe

 0.1%

 Mn

 11%

 P

 16%

 Ca

 0.3%

 Mg

 0.7%

 Mn

 0.5%

 PP

 3.3%

 Co

 1%

 Ca

 0.3%

 Ni

 1.7%

 C

 5.1%

 Graphite

 5%

 Mn

 18.6%

 Li

 28%

 Na

 0.01%

 C

 5.1%

 Cu

 10%

 C

 3.1%

 Li

 25%

 Al

 6%

 Li

 3.4%

 Cu

 10%

 PP

 3.3%

 PP

 3.3%

 Al

 6%

 Graphite

 7.1%

 Cu

 10%

 Graphite

 6% 

 Ni

 8.1%

Al

 6%

 PU

 3.1%

 Lix

 9%

Lix

 8%

 Lix

 9%

 F

 3.1%

 F

 3.3%

 F

 3.1%

 

3 – HAZARDS IDENTIFICATION

3.1 Physical :
The Lithium-Ion rechargeable batteries described in this Material Safety Data Sheet are sealed units which are not hazardous when used according to the recommendations of the manufacturer.

Under normal conditions of use, the solid electrode materials and liquid electrolyte they contain are non- reactive provided the battery integrity is maintained and seals remain intact. There is Risk of fire only in cases of abuse (mechanical, thermal, electrical), which leads to the activation of the safety valve and/or the rupture of the battery container. Electrolyte leakage, electrode materials reaction with moisture/water or battery vent/fire may follow, depending upon the circumstances.
In case of excessive internal pressure and/or temperature Thunder Sky batteries are fitted with a safety vent for protection and/or rupture of the cell case.

3.2 Chemical
Classification of dangerous substances contained into the product as per directive 67/548/EEC

Substance

 

Melting point Boiling point

Classification

 

CAS N 0

Chemical Symbol

 

 

Exposure limit

Indication
of danger

Special
risk (1)
Safety
advices (2)

12190-79-3

LiFCoO 2
LiFFePO4
LiFMn2O4

> 1000 o C

N/A

 

 

R 22
R43

S2 S22
S24 S26 S36
S37 S43 S45

EC: 96-49-1
DMC: 616-38-6
DEC: 105-58-8
EA: 141-78-6

Organic
solvents
(DC-DMC DEC-EA)

EC: 38 ° C
DMC: 4 ° C
DEC:-43 ° C
EA: -84 ° C

EC: 243 ° C
DMC: 90 ° C
DEC: 127 ° C
EA: 77 ° C

None
established
OSHA

Flammable

R21 R22 R41 R42/43

S2 S24
S26 S36
S37 S45

21324-40-3

LiPF 6

N/A
(decomposes at 160 ° C)

N/A

None
established
OSHA

Irritant
Corrosive

R14
R21 R22
R41 R43

S2 S8 S22
S24 S26 S36
S37 S45

1 – Nature of Special risks:
R14 Reacts with water.
R 21 Harmful in contact with skin.
R22 Harmful if swallowed.
R41 Risk of serious damage to the eye.
R42/43 May cause sensitization by inhalation and skin contact.
R43 May cause sensitization by skin contact.

 2 – Safety advices:
S 2 Keep out of reach from children.
S 8 Keep away from moisture.
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical attention.
S36 Wear suitable gloves.
S 45 In case of incident, seek medical attention

4 - FIRST AID MEASURES
In case of battery rupture,fume or fire, evacuate personnel from contaminated area and provide maximum ventilation to clean out fumes/gases. Meantime, spray the battery with water or put the smoking battery into basin at once.
In all cases, seek medical attention.
Eye contact: Flush with plenty of water (eyelids held open) for at least 15 minutes.
Skin contact : Remove all contaminated clothing and flush affected areas with plenty of Water and soap for at least 15 minutes Do not apply greases or ointments.
Ingestion: Dilute by giving plenty of water and get immediate medical attention. Assure that the victim does not aspirate vomited material by use of positional drainage.Assure that mucus does not obstruct the airway. Do not give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air and ventilate he contaminated area. Give oxygen or artificial respiration if needed.

5 – FIRE-FIGHTING MEASURES
Fire and fume hazard: Except LYP series batteries, LCP and LMP batteries can leak and/or spout vaporized or decomposed and combustible electrolyte fumes in case of exposure above 150 ° C resulting from inappropriate use, abuse, or from the environment. Possible formation of hydrogen fluoride (HF) and phosphorous oxides during fire. LiPF 6 salt contained in the electrolyte releases hydrogen fluoride (HF) in contact with water.

Extinguishing media: spray the battery with water or put the smoking battery into basin at once.
Can be used : ………… Type D extinguishers , Co2, Dry chemical or Foam extinguishers
Special hazards : Following cell overheating due to external source or due to improper use, electrolyte leakage or battery container rupture may occur and release inner component/material in the environment.
Eye contact : The electrolyte solution contained in the battery is irritant to ocular tissues.
Skin contact: The electrolyte solution contained in the battery causes skin irritation.
Ingestion: The ingestion of electrolyte solution causes tissue damage to throat and gastro/respiratory tract.
Inhalation : Contents of a leaking or ruptures battery can cause respiratory tract, mucus, membrane irritation and edema.

Special protection: Use self-contained breathing apparatus to avoid breathing irritant fumes.
Wear protective clothing and equipment to prevent body contact with electrolyte solution.

6 - ACCIDENTAL RELEASE MEASURES

The material contained within the batteries would only be expelled under abusive conditions.

Soak under water or spray with copious amounts of water , place in approved container (after cooling if necessary) and dispose in accordance with local regulations.

7 - HANDLING AND STORAGE

The batteries should not be opened, destroyed nor incinerate since they may leak or rupture and release in the environment the ingredients they contain. .

Handling: Do not crush, pierce, short (+) and (-) battery terminals with conductive (i.e. metal) goods. Do not directly heat or solder. Do not throw into fire. Do not mix batteries of different types and brands. Do not mix new and used batteries. Keep batteries in non-conductive (i.e. plastic) trays.

Storage: Store in a cool (preferably below 30 ° C) and ventilated area away from moisture, sources of heat, open flames, food and drink. Keep adequate clearance between walls and batteries. Temperature above 100 ° C may result in battery leakage and rupture. Since short circuit can cause burn, leakage and battery container rupture hazard, keep batteries in original packaging until use and do not jumble them.

Other: Follow manufacturer recommendations regarding maximum recommended currents and operating temperature range.

Applying pressure or deforming the battery may lead to the rupture of battery container and disassembly followed by eye, skin and throat irritation.

8 - FIRE CONTROLS/PERSONAL PROTECTION

Respiratory protection: Not necessary under normal use. In case of battery rupture, use self- contained full-face respiratory equipment.

Hand protection: Not necessary under normal use. Use Viton rubber gloves if handling a leaking battery.

Eye protection: Not necessary under normal use. Wear safety goggles or glasses with side shields if handling a leaking or ruptured battery.

Skin protection: Not necessary under normal use. Use rubber apron and protective working in case of handling of a ruptured battery.

9 - PHYSICAL AND CHEMICAL PROPERTIES

9.1 Appearance : (Physical shape and color as supplied)White Plastic Prismatic cases with ribs, hermetically sealed and fitted with a metallic terminals/connections.

9.2 Temperature range :

 

Continuous

Occasional

In storage during
discharge during
during charge

+ 30 ° C max
•  30/+ 80 ° C
0/+ 75 ° C

-30/+ 80 ° C
-30/+80 ° C
0/+75 ° C

9.3 Specific energy: (Note: Wh = Normal voltage x Rated Ah) kg = Average battery weight)

9.4 Specific pulse power: 600w-1200w/kg Varies depending upon size

9.5 Mechanical resistance : As defined in relevant IEC standard

10 - STABILITY AND REACTIVITY

Conditions to avoid : Heat above80 ° C or incinerate. Deform, mutilate, crush, pierce, disassemble. Short circuit. Prolonged exposure to humid conditions.

Materials to avoid : N/A

Hazardous decomposition products: Corrosive/Irritant Hydrogen fluoride (HF) is produced in case of reaction of lithium hexafluorophosphate (LiPF 6 ) with water. Combustible vapors and formation of Hydrogen fluoride (HF) and phosphorous oxides during fire.

11 - TOXOLOGICAL INFORMATION

Thunder Sky Battery Ltd. Lithium-Ion rechargeable batteries do not contain toxic materials.

12 - ECOLOGICAL INFORMATION

When properly used or disposed, Thunder Sky Battery Ltd Lithium-Ion rechargeable batteries can be recycled and do not present environmental hazard during their life time.

13 - DISPOSAL CONSIDERATIONS

Dispose in accordance with applicable regulations, which vary from country to country.

Lithium-Ion batteries should have their terminals insulated and be preferably wrapped in individual plastic bags prior to disposal.

13.1 Incineration :

Incineration should never be performed by battery users but eventually be trained professionals in authorized facilities with proper gas and fumes treatment.

13.2 Recycling : Send to authorized recycling facilities.

14 - TRANSPORT INFORMATION

14.1 United Nations : UN ° 3090 Classification 9 Packaging ICAO 903 for Air Transport IMDG 903 for Sea Transport

14.2 Internations conventions :

Air IATA Yes

Sea IMDG Yes

Land ADR (road) Yes

RID (rail) Yes

14.3 Other : In the USA : Code of Federal Regulations (49 CFR Ch. 1 § 173-185)

15 - REGULATION INFORMATION

The transport of rechargeable lithium-ion batteries is regulated by various bodies

(IATA, IMO, ADR, US- DOT) that follow the United Nations “ Recommendations on

the Transport of Dangerous Goods, Model Regulations, 13 th Revised edition –

2003 – Ref. STSG/AC.10/1 Rev. 13 ”

Depending on their lithium metal equivalent weight content, design, and ability to pass safety tests defined by the UN in the “ Recommendations on the Transport of Dangerous Goods – Manual of Tests and Criteria – 3 rd Revised edition – 2002 – Ref. Ref. STSG/AC.10/11 Rev. 3 Amendment 1 <> ” , the lithium-ion cells and the battery packs may or may not be assigned to the UN No 3090 Class-9, that is restricted for transport.

Individual lithium-ion cells and battery packs with respectively less than 1.5 and 8 grams of equivalent Lithium metal content that pass the UN-defined safety tests, are not restricted for transport (1.0 Ah of declared nominal capacity = 0.3 gram of Li equivalent weight content).

16 – OTHER INFORMATION/DISCLAIMER

This information has been compiled from sources considered to be dependable and is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty (either expressed or implied) or guarantee is made to the accuracy, reliability or completeness of the information contained herein.

This information relates to the specific materials designated and may not be valid for such material used in combination with any other materials or in any process. It is the user’s responsibility to satisfy himself as to the suitability and completeness of this information for his particular use.

Thunder Sky does not accept liability for any loss or damage that may occur whether direct, indirect, incidental or consequential, from the use of this information. Thunder Sky does not offer warranty against patent infringement. Additional information is available by calling the telephone number above designated purpose.

 

 

 

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